Assessment of Aliphatic Hydrocarbons in Soils from Selected Areas in Agbarho Communities, Delta State, Nigeria
Keywords:
aliphatic hydrocarbons, molecular weight, molecular indices, Agbarho communityAbstract
Communication in Physical Sciences, 2022, 8(3):412 - 422
Authors: Wisdom Ivwurie, and Gabriel A. Akindeju
Received: 20 February 2022/Accepted 28 August 2022
The occurrence of petroleum hydrocarbons in the environment has been remarkably discouraging in recent times due to the impeding toxicity of most hydrocarbons. In this study, the presence of aliphatic hydrocarbons was assessed in primary sources and in anthropogenic impacted soils within the Agbarho communities in Delta State, Nigeria. The petroleum hydrocarbons were quantified using gas chromatography equipped with flame ionization detector (GC-FID) after extraction and clean-up of the extracts with nhexane/dichloromethane (1:1 v/v). The evaluated concentrations of the total aliphatic hydrocarbons in the primary
sources ranged from 1,788,030 to 5,368,702µg kg-1 while the concentrations of the total hydrocarbon were within the range, 813 to 11900 µg kg-1 . Source activities variation in the concentrations of the total aliphatic hydrocarbon in anthropogenic impacted
soils was observed to followed the following trend, Mechanic Workshop Soil > Barbecue spot soil > Filling Station Soil > Motor Way
Soil > Traffic point soil. On the average, the concentrations of the higher molecular weight n-alkanes (> C31 in the studied soils) were the highest. Evaluated molecular indices of the investigated aliphatic hydrocarbons showed that the aliphatic hydrocarbons in these soils might have originated from different anthropogenic sources such as petrogenic and terrestrial biogenic sources.
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References
Adedosu, T. A., Adedosu, H. O., Sojinu, O. S., & Olajire, A. A. (2012). N-Alkanes and polycyclic PAHs (PAHs) profile of soil from som polluted sites in Niger Delta, Nigeria. Environmental Earth Science, 68,pp. 2139-214. doi:1101007/S12665-0121897-3
Adipah, S. (2019). Introduction of petroleum hydrocarbons contaminants and its human effects. Journal of Environmental Science
and Public Health 3, pp. 001-009.
Aly Salem, D. M. S., Morsy, F. A. E. M., El Nemr, A., El-Sikaily, A. & Khaled, A. Communication in Physical Sciences, 2022, 8(3):413-422 421
(2014). The monitoring and risk assessment of aliphatic and aromatic hydrocarbons in sediments of the Red Sea, Egypt. Egyptian Journal of Aquatic Research, 40, 4, pp. 333–348.
Bourbonniere, R. A. & Meyer, P. A. (1996). Anthropoenic influences on hydrocarbon contents of sediments deposited in eastern
lake ontorio since 1800. Journal of Environmental Earth Science 28, 1, https://doi.org/10.1007/S002540050074
Emoyan O. O., Ikechukwu, C. C. & Tesi, G. O. (2020a). Occurrence and sources of AHC in anthropogenic impacted soils from
petroleum tank-farms in the Niger Delta,Nigeria. Ovidius University Annals of Chemistry, 31, 2, pp. 132 – 144.
Emoyan, O.O., Tesi, G.O., Ohwo, E. & Odali, E.W. (2021). Quantification, sources, and associated risks of 16-priority polycyclic
aromatic hydrocarbons from selected land-use impacted soils. Ovidius University Annals of Chemistry, 32, 1, pp.
:62
Gao, X. & Chen, S. (2008). Petroleum pollution in surface sediments of Daya Bay, South China, revealed by chemical fingerprinting of aliphatic and alicyclic hydrocarbons. Estuarine Coastal Shelf Science, 80, pp. 95-102
Gennadiev, A. N., Pikovskii, Y. I., & Tsibart, A.S (2015). Hydrocarbons in soils: Origin, composition,and behavior (Review) Euroasian Soil Science, 48, pp. 1076–1089..https://doi.org/10.1134/S1064229315100026
Gonul, L. T. & Kucuksezgin, F. (2012). Aliphatic and polycyclic aromatic hydrocarbons in the surface sediments from the Eastern Aegean: assessment and source recognition of petroleum hydrocarbons. Environmental Science and Pollution Research Internatinal, 19, 1, pp.
-41. doi: 10.1007/s11356-011-0524-2
Ilechukwu, I., Onyema, M. O. & Tejano, G. I. (2019). Sources and variations of aliphatic hydrocarbons in petroleum products contaminated soils. Journal of Applied Sciences; 19, 6, pp. 624-628.
Ivwurie, (2004). Source apportionment and use of hydropyrolysis to elucidate sources of heavily biodegraded hydrocarbons.
Journal of Science and Multidisciplinary Research, 8, 1, pp. 13–8
Iwegbue, C.M.A., Bebenimibo, E., Obi, G., Tesi, G.O., Olisah, C., Egobueze, F. E. & Martincigh, B.S. (2021). Distribution and sources of n-Alkanes and polycyclic aromatic hydrocarbons in sediments around oil production facilities in the Escravos River Basin, Niger Delta,
Nigeria. Archives of Environmental Contamination and Toxicology, https://doi.org/10.1007/s00244-021-00810-w.
Iwegbue, C.M.A., Aganbi, E., Obi, G., Osakwe, S.A., Eguvbe, P., Ogala, J., & Martincigh, B.S (2016b). Aliphatic hydrocarbon profiles in sediments of the Forcados River, Niger Delta, Nigeria. Environmental Forensics, 17, 2, pp. 144-155.
Mille, G., Asia, L., Guiliano, M., Malleret, L.& Doumenq, P. (2007). Hydrocarbons in coastal sediments from the Mediterranean
Sea (Gulf of Fosarea, France). Marine Pollution Bulletin, 54, pp. 566–575.
Sakari, M., Zakaria, M. P., Lajis, N. H., Mohamed, C. A. R. & Abdullah, M. H.(2012). Reconstruction of aliphatic hydrocarbons history and sources from sedimentary record of the Johor Strait,Malaysia. Coastal Marine Science, 35,pp. 142–152.
Sakari, M., Zakaria, M. P., Lajis, N. H.,Mohamed, C. A. R., Bahry, P. S. & Anita,S. (2008). Characterization, distribution,sources and origins of aliphatic hydrocarbons from surface sediment of Prai Strait, Penang, Malaysia: A Communication in Physical Sciences, 2022, 8(3):413-422 422 widespread anthropogenic input.Environment Asia, 2, pp. 1–14.
Udoinyang, U., Dennis, E. & Akabio, J. H. U.(2019). Petroleum Hydrocarbon Contents in Tropical Soils near Crude Oil Exploration and Processing Site in Niger Delta, Nigeria. Journal of Environmental Science Current Research, 2,007. doi. 10.24966/ESCR-5020/100007
United Nations Environment Programme (UNEP) (1995), Determination of petroleum hydrocarbons in sediments. Reference Methods for Marine Pollution Studies No.72.
United States Environmental Protection Agency (US EPA 1996). Method 8015B. Nonhalogenated organics using GC/FID.
Washington: Volkman JK, Holdswoeth DG, Neill GP, Bavor HJ (1992). Identification of natural, anthropogenic and petroleum
hydrocarbons in aquatic sediments. The Science of Total Environment 112: 203–219.
Yusoff, H.B., Assim, Z.B. and Mohamad, S.B. (2012). Aliphatic hydrocarbons in surface sediments from South China Sea off
Kuching Division, Sarawak. Mala. J. Anal. Sci. 16: 1–11.
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