Bio/fossil fuels refining Appraisal of the Elemental distributions, SiO4 /AlO4 and Si/Al Ratios of Itu Virgin Kaolin
Keywords:
Kaolin, calcination, silica (sio2), alumina (Al2O3), zeoliteAbstract
Communication in Physical Sciences, 2023, 10(3):171-181
Authors: Godwin J. Udo, Emaime J. Uwanta, Joachim J. Awaka-Ama, Emmanuel E. Ubuo, Emmanuel J. Ukpong, Raphael Igwe, Aniedi E. Nyong, Nsikan J. Etukudo and Stephen D. Okon
Received: 03 May 2023/Accepted 24 December 2023
There is some evidence from the literature supporting the abundant deposit of untapped kaolin clay in various locations in Itu, Akwa Ibom State, Nigeria. Due to some established industrial applications of kaolin including catalysis, adsorption, ceramics, paper production, coating, plastic fillers, paint extenders, cement and ion-exchangers among others, the need to explore their presence in a given environment and the grade of kaolin present is necessary. Consequently, the present study is designed to evaluate the composition and implications of this mineral in the stated environment concerning their SiO4 /AlO4 and Si/Al ratios and also the elemental distributions in Itu virgin kaolin framework The results from the XRF analysis indicated varying concentrations of SiO2, Fe3O2, K2O, Al2O3, TiO2 and TiO2 with O, Al, Si, K, Ti, Fe, and Fe as the major chemical compounds. The calculated molar ratio of SiO2/Al2O3 and Si/Al were found to be 2.244: 2.690 and 3.564:2.052, respectively. Based on these results there high tendency that the samples can be modified to form zeolite for biofuel purification.
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Kassa, A. E., Shibeshi, N. T., Tizazu, B. Z.. & Prabhu, S. V. (2022) Characteristic Investigations on Ethiopian Kaolinite: Effect of Calcination Temperature on Pozzolanic Activity and Specific Surface Area. Hindawi Advances in Materials Science and Engineering. 2022, 2, 8, 2-8. https://doi.org/10.1155/2022/2481066
Beckhoff, B., Kanngießer, B., Langhoff, N., Wedell R. & Wolff., H. (2007) Handbook of practical X-ray fluorescence analysis, Springer Science & Business Media.
Bassey, B. E., Opara, K. N. & Usip, L. P. (2020). Morphological and molecular characterization of endophilic Anopheles gambiae complex, in Itu Local Government Area,Akwa Ibom State, Nigeria. Nigerian Journal of Parasitology 41, 1, pp. 70-78
Wang, Cheng, Shaozheng Leng, Huidong Guo, Jiale Yu, Wenjie Li, Liyun Cao, Jianfeng Huang (2019). Quantitative arrangement of Si/Al ratio of natural zeolite using acid treatment. Applied Surface Science, 498, 143874. https://doi.org/10.1016/j.apsusc.2019.143874
Zhu, D., Wang, L., Cui, W., Tian, J., & Liu, Z. (2022). High-silica zeolite Y: seed-assisted synthesis, characterization and catalytic properties Inorg. Chem. Front , 9, pp. 2213–2220.
Elimbi, A., Tchakoute H.K., Njopwouo D. (2011). Effects of calcination temperature of kaolinite clays on the properties of geopolymer cements, 25(6), 2805–2812. doi:10.1016/j.conbuildmat.2010.12.055
Elueze, A.A., Ntekim E.E., Ekwere, S.J. (1999). Compositional and Industrial Assessment of ClayBodies in Itu Area, South Eastern Nigeria. J. of Min. and Geo., (35): 117-124
Udo, Godwin James, Edemumo Emmanuel Etim., Joachim J. Awaka-Ama, Emmanuel E. Ubuo, Emmanuel J. Ukpong, Emaime J. Uwanta and Aniedi E. Nyong (2023). Synthesis and Characterization of Di-Metallic Zeolite Pt-Co Composite as Potential Catalyst for Reforming and Hydro-Desulphurization of Gasoline. Mater. Sci. Res. Rev., 6(4):720-729
Udo, Godwin James, Usoro M. Etesin, Joachim J. Awaka-Ama, Aniedi E. Nyong, Emaime J. Uwanta (2020). GCMS and FTIR Spectroscopy Characterization of Luffa CylindricaSeed Oil and Biodiesel Produced from the oil. Communication in Physical Sciences 2020, 5(3): 378-390.
Udo, Godwin James, Joachim J. Awaka-Ama, Emaime J. Uwanta, Ifiok O. Ekwere and
Igwe R. Chibueze (2020). Comparative Analyses of Physicochemical Properties of
Artisanal Refined Gasoline and Regular Automotive Gasoline. Front. Chem. 8(753):1-7,doi:10.3389/fchem.2020.007-553.
Agostini, G., Lamberti, C., Palin, L., M. Milanesio, N. Danilina, B. Xu, M. Janousch and J. A. Van Bokhoven (2010). In Situ XAS and XRPD Parametric Rietveld Refinement To Understand Dealumination of Y Zeolite Catalyst J. Am. Chem. Soc, 132, 667–678
Isaac, Ukeme O., Isaac, Ibanga O., Itoro E. Willie, Etiyene I. Essiet, Rasheed Babalola, and Udo J. Ibok (2023). Communication in Physical Sciences, 2023, 10(1): 40-56Modifications, Surface Morphology, and Mineral Composition of Clay Obtained from Southern Nigeria, Communication in Physical Sciences, 10 (1): 40-56
Jialiang Li, Mingkun Gao, Wenfu Yan and Jihong Yu (2023) Regulation of the Si/Al ratios and Al distributions of zeolites and their impact on properties. Chem. Sci.(2023)14, 1935-1959
Meng, B., Ren, S., Li, Z., Nie, S., Zhang, X., Song, W., Guo, Q. and Shen, B. (2021). A facile organic-free synthesis of high silica zeolite Y with small crystal in the presence of Co2+ Microporous Mesoporous Mater., 2021, 323, 111248.
Murray, H. (2007). Applied clay mineralogy. 1stedition, Copyright © Elsevier B.V., ISBN-13: 978-0- 444-51701-2
M. D. Oleksiak, K. Muraoka, M. F. Hsieh, M. T. Conato, A. Shimojima, T. Okubo, W. Chaikittisilp and J. D. Rimer, Angew (2017). Organic-Free Synthesis of a Highly Siliceous Faujasite Zeolite with Spatially-Biased Q4 (nAl) Si Speciation. Chem., Int. Ed., 56, 13366–13371.
Marcos Antonio Klunk, Mohuli Das, Sudipta Dasgupta, Andrea Natale Impiombato, Nattan Roberto Caetano, Paulo Roberto Wander and
Carlos Alberto Mendes Moraes (2020). Comparative study using different external sources of aluminum on the zeolites synthesis from rice husk ash. Materials Research Express, 7( 1) DOI 10.1088/2053-1591/ab608d
Nyong, A., Nsi, E., Awaka-Ama, J & Udo, G. (2020). Comparative Evaluation of the Photodegradation of Stearic Acid by TiO2 - Modified Cement under UV Irradiation Through Water Contact Angle and Absorbance Studies. Advances in Material, 9(, 1, pp. 1-7
Obotowo, William Obot, Emmanuel Udama Odeh, Aniekan Okon, Mfon Udo Obot (2021) Mineralogy of Clays from Ikot Ebom Itam, Akwa Ibom State Nigeria. International Journal of Innovative Research in Sciences and Engineering Studies, 1(2):28-34
Zhang, R. Zou, W. Li, Y. Chang and X. Fan (2022) On understanding the sequential post-synthetic microwave-assisted dealumination and alkaline treatment of Y zeolite Microporous Mesoporous Mater. (2022) 333: 111736.
R. Pilar, J. Moravkova, G. Sadovska, S. Sklenak, L. Brabec, J. Pastvova and P. Sazama, (2022) Controlling the competitive growth of zeolite phases without using an organic structure-directing agent. Synthesis of Al-rich *BEA. Microporous Mesoporous Mater.,2022, 333, 111726.
Ubuo, Emmanuel E., Inimfon A. Udoetok, Andrew T. Tyouwa, Clement O. Obadimu, and Hamza S. Al-Shehri. "Capillary Rise: A Simple Tool for Simultaneous Determination of Porosity and Thickness of Thin Silica Coatings." Journal of Composites Science 7, no. 6 (2023): 259.
Udochukwu Mark, Charles Nwachukwu Anyakwo, Okechukwu Onyebuchi Onyemaobi, Chijioke Samson Nwobodo (2019). Effect of Calcination Condition on Thermal Activation of Ibere Clay and Dissolution of Alumina International Journal of Nonferrous Metallurgy, 8(2), , 9-24. DOI: 10.4236/ijnm.2019.82002
Zeolite Market Size, Share & Trends Analysis Report By Application (Catalyst, Adsorbent, Detergent Builder), By Product (Natural, Synthetic), By Region (North America, Europe, APAC, CSA, MEA), And Segment Forecasts, 2022–2030, Report 978-1-68038-601-1, Grand View Research Search PubMed
Li, X., Peng, K., Chen, H. & Wang, Z. (2018) TiO2 nanoparticles assembled on kaolinites with different morphologies for efficient photocatalytic performance. Sci. Rep. 8:11663.
Worasith, N., Goodman, B. A., Jeyashoke, N. & Thiravetyan, P. (2011). Decolorization of rice bran oil using modified kaolin. J. Am. Oil Chem. Soc. 88 :2005–2014.
Shafiq, N., Nuruddin, M. F., Khan, S. U. & Ayub, T. (2015). Calcined kaolin as cement replacing material and its use in high strength concrete. Constr. Build. Mater. 81:313–323.
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