The Redox Reaction between Di-μ-Oxo-Tetrakis (2, 2’- bipyridine) – Dimanganese (III, IV) Perchlorate and 1, 3-Dihydroxybenzene in Hydrochloric Acid
Keywords:
Redox reaction, 1,3-dihydroxybenzene, di-μ-oxo-tetrakis (2, 2’- bipyridine) – dimanganese (III, IV) perchlorateAbstract
The redox reaction between di-μ-oxo-tetrakis (2, 2’- bipyridine) – dimanganese (III, IV) perchlorate 3+ and 1,3-dihydroxybenzene ( Q) in hydrochloric acid was investigated using spectroscopic technique. The stoichiometry of the reaction was 2:3 for 3+: Q. The rate of reaction was first order with respect to both species while the overall rate of reaction was second order. Investigation of the effect of ionic strength on the reaction gave evident for non-dependence of the rate of reaction on change in dielectric constant, D, of the medium. The rate of the reaction increased with increase in the concentration of the acid and was found to be unaffected by the addition of added (Ni2+, NO3- and HCOO-) ions. There was no gel-formation in the course of the reaction and Michaelis-Menten’s type plot gave a straight line starting from the origin.
Downloads
Published
2020-09-25
Issue
Section
Articles
How to Cite
The Redox Reaction between Di-μ-Oxo-Tetrakis (2, 2’- bipyridine) – Dimanganese (III, IV) Perchlorate and 1, 3-Dihydroxybenzene in Hydrochloric Acid. (2020). Communication In Physical Sciences, 6(1), 738-745. https://journalcps.com/index.php/volumes/article/view/399
Most read articles by the same author(s)
- Patricia Ese Umoru, Femi Emmanuel Awe, Joseph Ifeanyi Uche, Oluwayemi Abiodun Babatunde, Ibrahim Aliyu Salaha, Investigation of the Adsorptive And Inhibitive Properties Of Cucurbita Maxima Peel Extract And Halide Ions As Inhibitors For Stainless Steel in 1m H2so4 Solution , Communication In Physical Sciences: Vol. 10 No. 2 (2023): VOLUME 10 ISSUE 2
Similar Articles
- A. E. Usoro, Comparing the Performance of Alternative Generalised Autoregressive Conditional Heteroskedasticity Models in Modelling Nigeria Crude Oil Production Volatility Series , Communication In Physical Sciences: Vol. 4 No. 2 (2019): VOLUME 4 ISSUE 2
- Felicia Uchechukwu Okwunodulu, Stella Mbanyeaku Ufearoh, Amaku James Friday, Angela Nwamaka Anim, Colorimetric detection of Hg(II) ions present in industrial wastewater using zinc nanoparticle synthesized biologically with Rauwolfia vomitoria leaf extract , Communication In Physical Sciences: Vol. 5 No. 4 (2020): VOLUME 5 ISSUE 4
- Felicia Uchechukwu Okwunodulu, Okechukwu Chimereoke Lord Ubani, Immaculate Nnedimma Onaka, Emeka Junior Chika, Kinetic studies on the sequestration of Pb2+ and Ni2+ ions in aqueous solutions using manganese nanoparticles anchored in ixora coccinea , Communication In Physical Sciences: Vol. 12 No. 8 (2025): VOLUME 12 ISSUE 8
- Benjamin Odey Omang, Temple Okah Arikpo, Eyong Gods’will Abam, Godwin Terwase Kave, Asinya Enah Asinya, Anthony Adesoji Onasanwo, The Geochemistry and Petrogenesis of the Iron-Bearing Sediments of Mfamosing, Southeastern (SE), Nigeria: Evidence from Major Oxides and Its Implication for Industrial Utilization , Communication In Physical Sciences: Vol. 11 No. 4 (2024): VOLUME 11 ISSUE 4
- Okoche K. Amadi, Uloma O. Akoh, Innocent A. Okoro, Egwuobasi Nwabuokechi,, Decontamination of Pb2+, Cd2+ and Ni2+ Polluted Water by Adsorption Unto Butterfly Pea (Centrosema pubescens) Seed Pod , Communication In Physical Sciences: Vol. 6 No. 1 (2020): VOLUME 6 ISSUE 1
- Emmanuel Acquah, Identification of Internal, Corona, and Surface Discharges in Electrical Insulation Through their Characteristics: A Case Study in Norfolk , Communication In Physical Sciences: Vol. 13 No. 2 (2026): VOLUME 13 ISSUE 2
- Olumide Oni, Kenechukwu Francis Iloeje, Optimized Fast R-CNN for Automated Parking Space Detection: Evaluating Efficiency with MiniFasterRCNN , Communication In Physical Sciences: Vol. 12 No. 2 (2025): VOLUME 12 ISSUE 2
- Rakiya Haruna, Muneer Aziz Saleh, 222Rn activity concentration in outdoor air of Johor, Malaysia , Communication In Physical Sciences: Vol. 8 No. 2 (2022): VOLUME 8 ISSUE 2
- Ola-Buraimo Abdulrazaq Olatunji, Adeleye Mutiu Adesina, Yusuf Aminu, Environmental Impact Assessment of Manganese Mining Activities On Groundwater, River Water, Land, and River sediments in Daranna, Bagudo Local Government Area, Kebbi State, Nigeria , Communication In Physical Sciences: Vol. 13 No. 3 (2026): Volume 13 Issue 3
- Cletus O. Ezidi, Eucharia N. Nwosu, Rita O. Ohakwe, Chukwunonso S. Okeke, Austin E. Aniecheonwu, Okwuchukwu E. Onyekaonwu, Chinyere E. Umeocho, Kingsley T. Agusiobo, Seed Yam Multiplication Using Minisett Technique , Communication In Physical Sciences: Vol. 11 No. 3 (2024): VOLUME 11 ISSUE 3
You may also start an advanced similarity search for this article.