Petrological, palynological analysis and Geochemistry of Maastrichtian Patti Shale in some parts of the southern Bida Basin, Nigeria: Implications for provenances and hydrocarbon studies

Authors

  • Godwin Okumagbe Aigbadon Federal University Lokoja, Kogi State, Nigeria
  • Azuka Ocheli University of Delta, Agbor, Delta State, Nigeria.
  • Tope Shade Alege Federal University Lokoja, Kogi State, Nigeria
  • Esther Onozasi David Federal University Lokoja, Kogi State, Nigeria

Keywords:

Geochemical analyses, gaseous hydrocarbon, organic matter, microfossil, production index

Abstract

Communication in Physical Sciences, 2023, 9(3):288-309

Authors: Godwin Okumagbe Aigbadon , Azuka Ocheli2,  Tope Shade Alege1, Esther Onozasi David1

Received: 01 April 2023/Accepted 08 July 2023/Published

The Patti Formations' shale and mudstones are the principal petroleum source rock of the Lokoja sub-Basin. Though only a
few works on Patti Shales in the Ahoko outcrops have been published, no significant work has been done in the Agbaja-Ibaru region of the basin. Arising from the need to analyze the provenances and hydrocarbon potentials of the shales of the Patti Formation in the basin, this study used petrological, palynological, and geochemical analyses. This study will employ
palynological, petrological (Scan Electron Microscope, SEM and X-ray diffractogram, XRD, X-ray fluorescence spectroscopy, XRF),
and geochemical techniques to assess the sources of the basin's rock potential and depositional environment. Field observations
results revealed the lithology of the Patti Formation to comprise siltstone, claystone, mudstones, and dark shales. According to the XRF results, the primary elemental oxides are SiO2, Al2O3, and Fe2O3. The X-ray diffraction (XRD) results for all shale samples examined revealed that the principal mineral components are quartz (32-49%), kaolinite (26-38%), and illite (0.2-5.26%). The shale is classified as quartzose shale because it has a high amount of quartz. The diagnostic palynoflora association showed the occurrence of Cingulatisporites ornatus, Tricolporopollenites sp., Monocolpites marginatus, Cyathidites minor, Distaverrusporites simplex, Longapertites sp., Rugulatisporites apparatus (Campanian), Tubistephanocolpites cylindricus, Longapertites microfoveolatus, Echitriporites trianguliformis, Cyathidites minor and Gleicheniidites sp., indicating Maastrichtian age and predominantly Continental (Terrestrial) environment of deposition. Total organic carbon (TOC) levels range from 0.46
to 2.56%, with a mean of 1.15%. The genetic potential (GP) ranges from 0.162 to 1.235Mg/g, with a mean of 0.619Mg/g,
indicating a moderate to relatively good source of the gas-rich rock. The hydrogen index (HI) varies from 7.8 to 173.9 mgHC/gTOC, with a mean of 67.29 mgHC/gTOC indicating Type III organic matter. The plots of producible hydrocarbon (S2) against TOC and HI against maximum temperature (Tmax) confirm the presence of type III (gas-prone) and type IV (inert) organic matter. As a result, the shale is slightly mature and successful at producing oil and gas.

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Author Biographies

Godwin Okumagbe Aigbadon, Federal University Lokoja, Kogi State, Nigeria

Department of Geology,

Azuka Ocheli, University of Delta, Agbor, Delta State, Nigeria.

Department of Geology,

Tope Shade Alege, Federal University Lokoja, Kogi State, Nigeria

Department of Geology,

Esther Onozasi David, Federal University Lokoja, Kogi State, Nigeria

Department of Geology,

References

Abimbola, A. F. (1997). Petrographic and paragenetic studies of the Agbaja Ironstone Formation, Nupe Basin, Nigeria. Journal of African Earth Sciences 25, pp. 169-181.

Abuhagazaa, A. A., Kassab, M. A., Wanas, H. A. & Teama, M. A. (2021). Reservoir quality and rock type zonation for the Sidri

and Feiran members of the Belayim Formation, in Belayim Land Oil Field, Gulf of Suez, Egypt. J Afri. Earth Sci, 181, 104242,

https://doi.org/10.1016/j.jafrearsci.2021.104242

Adeleye, D. R. (1973). Origin of ironstones: an example from the Mid-Niger Basin, Nigeria. J Sediment Petrol 43, pp. 709–727.

Adeleye, D. R. (1974). Sedimentology of the fluvial Bida sandstones (Cretaceous) Nigeria, Sedimentary Geology, 12, pp. 1- 24.

Adeleye, D. R. (1989). The Geology of the Middle Niger Basin, In Kogbe, C. A., (Ed.), Geology of Nigeria, 2nd edition, Rock View (Nigeria) Limited Jos, Nigeria, 335-339.

Adeniyi, J. O. (1985). Ground total magnetic intensity in parts of the Nupe Basin and the adjacent basement complex, Niger State,

Nigeria. Nigerian J. Appl. Sci. 3: 67–78.

Agyingi, C. M. (1993). Palynological evidence for a late Cretaceous age for Patti Formation, Eastern Bida Basin., Nigeria. J Afr Earth Sci, 17:513–523.

Aigbadon, G. O., Odoma, N. A., Obasi, I. A., Christopher, S. D., Nanfa, C. A., Baba Aminu, M. & Akakuru, O. C. (2022 a). Hydrocarbon prospectivity of the southern Bida and northern Anambra Basin, Nigeria using palynological and geochemical studies. J Geosystems & Geoenvirons 1,4,https://doi.org/10.1016/j.geogeo.2022.100103.

Aigbadon, G.O, Ocheli, A, Akakuru, C.O., Akudo, E. O., Christopher, S.D., Esharive, O., & Francis J A (2022b). Paleoenvironments and hydrocarbon reservoir potentials from the selected sedimentary basins in Nigeria using sedimentary facies and textural analyses. J Sed Environs. Doi:10.1007/s43217-022- 00101-x.

Aigbadon, G. O., Christopher, S. D., Akudo, E.O. & Akakuru, O.C (2022 c). Sedimentary facies and textural characteristics of Cretaceous sandstones in the southern Bida Basin, Nigeria: Implication for reservoir potential and depositional environment Energy Geoscience 3, pp. 323-341.https://doi.org/10.1016/j.engeos.2022.05.002

Aigbadon, G. O., Akakuru, O. C., Chinyem, F.I., Akudo, E. O., Musa, K. O., Obasi, A. I., Overare, B., Ocheli, A., Sanni, Z. J., Ahmed II, J. B., Onyekuru, S. O. & Muawiya, B. (2023 a). Facies analysis and Sedimentology of the Campanian- Maastrichtian sediments, southern Bida Basin, Nigeria. Carbonates and Evaporite,38, 27. https://doi.org/10.1007/s13146-023-00848-y.

Aigbadon, G. O., Igwe, E. O., Ocheli, A., Overare, B., Akakaru, O. C., Akudo, E. O., Obasi, A. I., Ahmed, J. B. & Baba Aminu, M. (2023 b). Sedimentary facies, paleoenvironments, paleogeography of the Upper Cretaceous succession in the southern Bida Basin, Nigeria. Arabian Journal of Geosciences 16, 349, https://doi.org/10.1007/s12517-023- 11390-5

Akande, S. O., Ojo, O. J., Erdtmann, B. D. & Hetenyi, M. (2005). Paleoenvironments, organic petrology and Rock-Eval studies on source rock facies of the Lower Maastrichtian Patti Formation, southern Bida Basin Nigeria. J. Afri. Earth Sci. 41, pp. 394-406.

Akande, S. O., Ojo, O. J. Adekeye, O. A. & Ladipo, K. O. (2006). A Geological Field Guide to the Southern Bida Basin. Nigerian Association of Petroleum Explorationists (NAPE), 24th Annual Conference and Exhibition, Abuja, 21 pp.

Benkhelil, J. (1989). The origin and Evolution of the Cretaceous Benue Trough, Nigeria, Journal of African Earth Sciences, 8 pp. 251-282.

Braide, S. P. (1992). Syntectonic fluvial sedimentation in the central Bida Basin. J Min Geol 28:55–64.

Braide, S. P. (1990). Petroleum Geology of the Southern Bida Basin, Nigeria. AAPG Am. Assoc. Pet. Geol.) Bull, 74( 5), 717pp.

Braide, S. P. (1992a). Geological development, origin, and energy mineral resources potential of the Lokoja Formation in the southern Bida Basin. Journal of Mining and Geology, 28, pp. 33-44.

Braide, S.P. (1992b). Syntectonic fluvial sedimentation in the central Bida Basin. Journal Mining and Geology. (28): 55–64.

Burke, K. (1976). The Chad Basin: an active intra-continental basin. Tectonophysics, 36, pp. 197–206.

Ehinola, O. A., Sonibare, O. O., Falana, A. M. & Javie, D. (2005). Organic geochemistry and biomarker evaluation of shale units of the Patti Formation, Bida Basin, Nigeria. NAPE Bull, 19, 1, pp. 78–88.

Fensome, R.A., Williams, G.L. (2004) The Lentin and Williams Index of Fossil Dinoflagellates. 2004 Edition: 909 pp.

Grant, N. K. (1978). Structural distinction between a metasedimentary cover and an underlying basement in the 600 my old Pan-African domain of North western Nigeria. Geol Soc Am Bull, 89, pp. 50–58.

Hunt, J. H (1996b). Petroleum geochemistry and geology, 2nd edn. W.H. Freeman and Company, New York.

Hunt, J. H. (1996a). Petroleum geochemistry and geology, 2nd edn. Freeman, New York, p 743.

Killops, S. D. & Killops, V. J. (1993). An introduction to organic geochemistry. Longman Group Ltd, UK

Kogbe, C. A. (1989). Geology of Nigeria. 2nd Edition, Rock View (Nigeria) Limited Jos, Nigeria. 538p.

Kogbe, C. A., Ajakaiye, D. E. & Matheis, G. (1983). Confirmation of Rift structure along the mid-Niger valley, Nigeria. J Afr Earth Sci 1, pp. 127–131.

Ladipo, K. O., Akande, S. O. & Mucke, A. (1994). Genesis of ironstones from the mid-Niger sedimentary basin: evidence from sedimentological, ore microscopic and geochemical studies. J Min Geol, 30, pp. 161–168.

Lawal, O. & Moullade, M. (1986). Palynological Biostratigraphy of Cretaceous Sediments in the Upper Benue Basin, N.E. Nigeria. Rev. de micropaleontologie, 29, 11, pp. 61-83.

Likasson, O. K. (1993). Application of Trend Surface Analysis to Gravity data over the Middle Niger Basin, Nigeria. Journal of Mining and Geology, 29, 2, pp. 11-19.

Nton, M. E. & Adamolekun, O. J. (2016). Sedimentological and Geochemical Characteristics of Outcrop Sediments of Southern Bida Basin, Central Nigeria: Implications for Provenance, Paleoenvironment and Tectonic History, Ife Journal of Science, 18, 2, pp. 345-369.

Nwajide, C. S. & Reijers, T, J. A. (1996). Sequence architecture in outcrops: examples from the Anambra Basin Nigeria, Nigerian Association of Petroleum Explorationists (NAPE) Bulletin. 11: 23-33.

Obaje, N. G. (2009). Geology and Mineral Resources of Nigeria, Springer, Heidelberg, 221p.

Obaje, N. G., Musa, M. K., Odoma, A. N. & Hamza, H. (2011). The Bida Basin in North-Central Nigeria: Sedimentology and Petroleum geology, Journal of Petroleum and Gas Exploration Research. 1, pp. 001-013.

Obaje, N. G., Wehner, H., Scheeder, G., Abubakar M. B., Jauro A. (2004). Hydrocarbon prospectivity of Nigeria's inland basins: from the viewpoint of organic geochemistry and organic petrology. AAPG Bull 87:325–353.

Ocheli, A., Aigbadon, G. O. & Abanjo, N. (2023). Subsurface Lithologies and Rock Eval Pyrolysis Analysis of Amansiodo-1 and Akukwa-1 Well sections, Nkporo Formation, Southeastern Part of the Anambra Basin, Nigeria: Implication for petroleum source rock potentials. Communication in Physical Sciences, 9 (2): 8082.

Ojo, O. J., Jimoh, A. Y., Umelo, J. C. &Akande, S.O. (2020). Organic geochemical and palynological studies of the Maastrichtian source rock intervals in Bida Basin, Nigeria: implications for hydrocarbon prospectivity. J Petrol Explor Product Technol, 10, pp. 3191–3206

https://doi.org/10.1007/s13202-020-00989-z

Ojo, S. B. & Ajakaiye, D. E. (1989). Preliminary interpretation of gravity measurements in the Mid-Niger Basin area, Nigeria. In: Kogbe, C.A. (Ed.), Geology of Nigeria. 2nd edition, Elizabethan Publishers, Lagos, pp. 347358.

Ojo, S. B., (1984). Middle Niger Basin Revisited, Magnetic constraints on Gravity Interpretations. Nigerian Mining and Geosciences Society Conference, Nsukka, Nigeria, Abstract. pp. 52-53.

Okeke, O. C. & Okogbue, C. O. (2011). Shales: A Review of their Classifications, Properties and Importance to the Petroleum Industry. Global Journal of Geological Sciences 9 (1): 55-73.

Okoro, A. U. (2007). Lithofacies and depositional environments of the bida sandstones, Bida Basin Nigeria. Journal of Applied and Natural Sciences (JANS), 1, pp. 64-70.

Ola-Buraimo, A.O. and Abdulganiyu, Y. (2017). Palynology and stratigraphy of the Upper Miocene Chad Formation, Bornu Basin, northeastern, Nigeria. Journal of Paleogeography, 6, 2, pp. 108-116.

Peters, K E., Walters, C. C. & Moldowan, J. M. (2005). The biomarker guide, 2nd edn. Cambridge University Press, Cambridge.

Petters, S. W. (1978). Middle Cretaceous paleoenvironments and biostratigraphy of the Benue Trough, Nigeria. Geol. Soc. Amer. Bull., 89, pp. 151–154.

Petters, S. W. (1986). Foraminiferal biofacies in the Nigerian rift and continental margin deltas. In Oti, M. N. and Postma, G. (Editor), Geology of Deltas. A. A. Balkema, Rotterdam. 219-235.

Pettijohn, F. J. (1957). Sedimentary rocks. Harper Bros, New York, N.Y., 2nd edn, 718.

Rahaman, M. A. O., Fadiya, S. L., Adekola, S. A., Coker, S. J., Bale, R. B., Olawoki, O. A., Omada, I. J., Obaje, N. G., Akinsanpe, O. T., Ojog, G. A. & Akande, W. G. (2019). A revised stratigraphy of the Bida Basin, Nigeria. J Afr Earth Sci, 151, pp. 67–81.

Schrank, E. (1992). Non marine Cretaceous correlations in Egypt and northern Sudan: palynological and palaeobotanical evidence, Cretaceous Research 13, pp. 351-368.

Schrank, E. (1994). Non marine Cretaceous Palynology of northern Kordofa, Sudan, with notes on fossil Salviniales (water ferns), Geologische Rundschau, 83, pp. 773-786.

Udensi, E. E. & Osazuwa, I.B. (2004). Spectral determination of depths to magnetic rocks under the Nupe Basin, Nigeria. NAPE Bull 17:22–27.

Whiteman, A. (1982). Nigeria: Its petroleum geology, resources and potential. 1 & 2 Graham and Trotman, London. 349.

Zaborski, P. M., (1998). A Review of the Cretaceous System in Nigeria, African Geosciences. 5, pp. 385-483.

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Published

2023-07-10