Investigation of the Inhibition of the Corrosion of carbon steel in Solution of HCl by Glimepiride

Main Article Content

*Nkem B. Iroha
Richard A. Ukpe

Abstract

Communication in Physical Sciences 2020, 5(3): 246-256


Authors: *Nkem B. Iroha and Richard A. Ukpe


Received 26 April 2020/Accepted 21 May 2020


The corrosion inhibition effect of glimepiride (GMP) on the corrosion of X70 carbon steel in 1 M HCl solution was investigated using weight loss, potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM) techniques. The inhibition efficiency was found to increase with increase in inhibitor concentration but decreased with temperature rise. The inhibition efficiency of glimepiride ranged from 54.2 to 95.8% for weight loss measurement, 52.0 to 90.5% for PDP and 53.3 to 90.3% for EIS method at 303 K. Polarization studies give evidence that GMP behaves as a mixed type inhibitor but predominantly anodic. Electrochemical impedance spectroscopy (EIS) spectra exhibit one capacitive loop indicating that, the corrosion reaction is controlled by charge transfer process. It was found that the investigated drug acts via adsorption on the carbon steel surface and obeys Langmuir and Temkin adsorption isotherms. Surface studies ascertain that a protective film was formed on the X70 carbon steel surface. The results have clearly shown that glimepiride has the inhibiting capacity for reducing the corrosion of X70 carbon steel in HCl solution.


 

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Author Biographies

*Nkem B. Iroha , Federal University Otuoke, P.M.B. 126 Yenagoa, Bayelsa State, Nigeria

Electrochemistry and Material Science Unit

Department of Chemistry

Richard A. Ukpe, Federal University, Otuoke, P. M. B. 126, Yenagoa, Bayelsa State, Nigeria

Department of Chemistry

References

Abdallah, M. (2004). Antibacterial Drugs as Corrosion Inhibitors for Corrosion of Aluminium in Hydrochloric Solution. Corros. Sci., 46, pp. 1981–1996.

Ahamed, K. R., Farzana, B. A., Diraviam, S. J., Dorothy, Rajendran, R. S. & Al-Hashem, A. (2019). Mild Steel Corrosion Inhibition by the Aqueous Extract of Commelina benghalensis Leaves. Port. Electrochim. Acta, 37, pp. 51-70

Ahamad, I. and Quraishi, M. A. (2010). Mebendazole: new and efficient corrosion inhibitor for mild steel in acid medium. Corrosion Science, 52, pp. 651-658.

Ameh, P. O.& Eddy, N. O. (2018). Theoretical and experimental investigations of the corrosion Inhibition action of Piliostigma thonningii extract on mild steel in acidic medium. Communication in Physical Sciences 3, 2, pp. 27-42.

Ameer, M. A. & Fekry, A. M. (2010). Corrosion inhibition of mild steel in acidic media using newly synthesized heterocyclic organic molecules. Int. J. Hydrogen Energy, 35, pp. 11387–11396.

Awe, F. E., Abdulwahab, M. & Otaru, H. A. (2019). Adsorptive studies of the inhibitive properties of ethanolic extracts of Parinari polyandra on mild steel in acidic media. Communication in Physical Sciences, 4, 1, pp. 49-57.

Bustamante, R. A., Silve, G. N., Quijano, M. A., Hernandez H. H., Romo, M. R., Cuan, A., Pardave, M. P. (2009) Electrochemical study of 2-mercaptoimidazole as a novel corrosion inhibitor for steels. Electrochim Acta, 54, pp. 5393–5399.

Chaieb, E., Bouyanzer, A., Hammouti, B. & Berrabah, M. (2009). Limonene as green inhibitor for steel corrosion in Hydrochloric Acid. Acta Phys. Chim. Sin., 25, pp. 1254.

Cookey, G. A., Tambari, B. L. & Iboroma, D. S. (2018). Evaluation of corrosion inhibition potentials of green tip forest lily (Clivia nobilis) leaves extract on mild steel in acid media. Journal of applied sci. Env.Mgt., 22, 1, pp. 90-94.

Daoud, D., Douadi, T., Hamani, H., Chafaa, S. and Al-noaimi, M. (2015). Corrosion inhibition of mild steel by two new s-heterocyclic compounds in 1 M HCl Experimental and computational study. Corrosion Science, 94, pp. 21-37.

Davis, S.N. (2004). The role of glimepiride in the effective management of Type 2 diabetes. J. Diabetes Complicat., 18, 6, pp. 367–76.

Eddy, N. O. & Ebenso, E. E. (2010). Corrosion inhibition and adsorption characteristics of tarivid on mild steel in H2SO4. E Journal of Chemistry, 7, S1, pp. S442-S448.

Eddy, N. O, Ibok, U. J., Ameh, P. O., Alobi, N. O.

& Sambo, M. M. (2014). Adsorption and quantum chemical studies on the inhibition of the corrosion of aluminum in HCl by Gloriosa superba (GS) gum Chemical Engineering Communications, 201, 10, pp. 1360-1383

Eddy, N. O. and Ita, B. I. (2011). Theoretical and experimental studies on the inhibition potentials of aromatic oxaldehydes for the corrosion of mild steel in 0.1 M HCl. Journal of Molecular Modeling 17, pp. 633-647

Eddy, N. O., Ameh, P. O., Gimba, E. E. & Ebenso, E. E. (2011a). GCMS studies on Anogessus leocarpus gum and their corrosion inhibition potential for mild steel in 0.1 M HCl. International Journal of Electrochemical Sciences, 6, pp. 5815-5829.

Eddy, N. O, Ekwumengbo, PA, Mamza, PAP (2009c) Ethanol extract of Terminalia catappa as a green inhibitor for the corrosion of mild steel in H2SO4 Green Chemistry Letters and Review 2, 4, pp. 223-231

Eddy, N. O., Ita, B. I., Dodo, S. N., Paul E. D. (2011b). Inhibitive and adsorption properties of ethanol extract of Hibiscus sabdariffa calyx for

the corrosion of mild steel in 01 M HCl Green Chemistry Letters and Review, 5, 1, pp. 43-53.

Eddy, N. O., Ameh, P. O. and Essien, N. B. (2018). Experimental and computational Chemistry studies on the inhibition of aluminum and mild steel in 0.1 M HCl by 3-nitrobenzoic acid. Journal of Taibah University for Science, 12 (5):545-556

El-Hajjaji, F., Merimi, I., El Ouasif, L., El Ghoul, M., Achour, R., Hammouti, B., Belghitia, M. E., Chauhand, D. S. & Quraishi, M. A. (2019). 1-

Octyl-2-(octylthio)-1H-benzimidazole as a New and Effective Corrosion Inhibitor for Carbon Steel in 1 M HCl. Port. Electrochim. Acta, 37,

pp. 131-145

Goulart, C. M., Esteves-Souza, A., Martinez-Huitle, C. A., Rodrigues, C. J. F., Maciel, M. A. M. and Echevarria, A. (2013). Experimental and

theoretical evaluation of semicarbazones and thiosemicarbazones as organic corrosion inhibitors. Corrosion Science, 67, pp. 281-291.

Hamilton-Amachree A, Iroha N. B. (2019) Corrosion inhibition of API 5L X80 pipeline steel in acidic environment using aqueous

extract of Thevetia peruviana. Chem Int 6:117- 128.

Hussin, M. H. & Kassim, M. J. (2011). The corrosion inhibition and adsorption behavior of Uncaria gambir extract on mild steel in 1M

HCl. Materials Chemistry and Physics, 125, pp. 461–468.

Iroha, N. B. & Hamilton-Amachree, A. (2019) Inhibition and adsorption of oil extract of Balanites aegyptiaca seeds on the corrosion of

mild steel in hydrochloric acid environment. World Sci New, 126, pp. 183-197.

Iroha, N. B. & James, A. O. (2018). Assessment of Performance of Velvet Tamarind-furfural resin as Corrosion Inhibitor for Mild Steel in Acidic Solution, J. Chem Soc. Nigeria, 43, 3, pp. 510 – 517.

Iroha, N. B. & James, A. O. (2019). Adsorption behavior of pharmaceutically active dexketoprofen as sustainable corrosion Inhibitor

for API X80 carbon steel in acidic medium. World News Nat Sciences, 27, pp. 22-37.

Iroha, N. B. & Nnanna, L. A. (2019). Electrochemical and Adsorption Study of the anticorrosion behavior of Cefepime on Pipeline

steel surface in acidic Solution. J. Mater. Environ. Sci. 10, 10, pp. 898-908.

Iroha, N. B., Chidiebere, M. A. (2017) Evaluation of the Inhibitive Effect of Annona Muricata .L Leaves Extract on Low-Carbon Steel Corrosion in Acidic Media. International Journal of Materials and Chemistry, 7, pp. 47-54.

Iroha, N. B. Oguzie, E. E. Onuoha, G. N. & Onuchukwu, A. I. (2005) Inhibition of Mild Steel Corrosion in Acidic Solution by derivatives of Diphenyl Glyoxal, 16th International Corrosion Congress, Beijing, China, pp. 126-131.

James, A. O. & Iroha, N. B. (2019). An Investigation on the Inhibitory Action of Modified Almond Extract on the Corrosion of Q235 Mild Steel in Acid Environment. IOSR Journal of Applied Chemistry, 12, 2, pp. 1-10

Jisha, M., Hukuman, N. H. Z., Leena, P. & Abdussalam, A. K. (2019). Electrochemical, computational and adsorption studies of leaf and floral extracts of Pogostemon quadrifolius (Benth.) as corrosion inhibitor for mild steel in hydrochloric acid. J. Mater. Environ. Sci., 10, 9, pp. 840-853.

Lagrene, M., Mernari, B., Bouanis, M., Traisnel M. & Bentiss, F. (2002). Study of the mechanism and inhibiting efficiency of 3,5-bis(4- methylthiophenyl)-4H-1,2,4-triazole on mild steel corrosion in acidic media. Corros. Sci., 44, 3, pp. 573-588

Ma, Y., Han, F., Li, Z. & Xia, C. (2016). Acidic- Functionalized Ionic Liquid as Corrosion Inhibitor for 304 Stainless Steel in Aqueous Sulfuric Acid. ACS Sustain. Chem. Eng., 4, 9,pp. 5046-5052.

Madueke, N. A. & Iroha, N. B. (2018). Protecting Aluminium Alloy of type AA8011 from Acid Corrosion Using Extract from Allamanda cathartica Leaves. International Journal of Innovative Research in Science, Engineering and Technology, 7, 10, pp. 10251-10258.

Mashuga, M. E., Olasunkanmi, L. O., Adekunle, A. S., Yesudass, S., Kabanda, M. M. & Ebenso, E. E. (2015). Adsorption, thermodynamic and quantum chemical studies of 1-hexyl-3- methylimidazolium based ionic liquids as corrosion inhibitors for mild steel in HCl. Materials, 8, 6, pp. 3607–3632.

Muthukrishnan, P., Prakash, P., Ilayaraja, M., Jeyaprabha, B. & Shankar, K (2015). Effect of Acidified Feronia elephantum Leaf Extract on the Corrosion Behavior of Mild Steel. Metallurgical and Materials Transactions B, 46b, pp. 1448-1460.

Musa, A. Y., Mohamad, A. B., Khadum, A. A. H. & Chee, E. P. (2011). Galvanic corrosion of aluminum alloy (Al2024) and copper in 1.0 M nitric acid. Int J Electrochem Sci, 6, pp. 5052-5065.

Onyeachu, I. B., Chauhan, D. S., Ansari, K. R., Obot, I. B., Quraishi M. A. & Alamri, A. H.

(2019). Hexamethylene-1,6-bis(N-D-glucopyranosylamine) as a novel corrosion inhibitor for oil and gas industry: electrochemical and computational analysis. New J. Chem., 43, pp. 7282-7293.

Singh, A. K. & Quraishi, M. A. (2010). Effect of Cefazolin on the corrosion of mild steel in HCl solution. Corrosion Science, 52, pp. 152–160.

Solmaz, R. (2010). Investigation of the inhibition effect of 5-((E)-4-phenylbuta-1,3-dienylideneamino)-1,3,4-thiadiazole-2-thiol Schiff base on mild steel corrosion in hydrochloric acid. Corros. Sci., 52, pp. 3321– 3330.

Tao, Z., Zhang, S., Li, W. & Hou, B. (2011). Adsorption and Inhibitory Mechanism of 1H-1,2,4-Triazol-l-yl-methyl-2-(4-chlorophenoxy) Acetate on Corrosion of Mild Steel in Acidic Solution. Ind. Eng. Chem. Res., 50, 10, pp. 6082–6088.

Tayebi, H., Bourazmi, H., Himmi, B., El Assyry A., Ramli, Y., Zarrouk, A., Geunbour. A., Hammouti, B., Ebenso, E. E. (2014) An electrochemical and theoretical evaluation of new quinoline derivative as a corrosion inhibitor for carbon steel in HCl solutions. Der Pharm Lett, 6, pp. 20–34.

Ukpe, R. A. (2019). Joint effect of ethanol extract of orange peel and halides on the Inhibition of the corrosion of aluminum in 0.1 M HCl: An approach to resource recovery. Communication in Physical Sciences, 4, 2, pp. 118-132

Verma, C., Quraishi, M. A., Ebenso, E. E., Obot, I. B. & El Assyry, A. (2016). 3-Amino alkylated indoles as corrosion inhibitors for mild steel in 1M HCl: Experimental and theoretical studies. Journal of Molecular Liquids. 219, pp. 647– 660.

Yadav, M., Kumar, S., Sinha, R. R. & Behera, D. (2013). Experimental and Quantum Chemical Studies on Corrosion Inhibition Performance of Benzimidazole Derivatives for Mild Steel in HCl. Ind. Eng. Chem. Res., 52, pp. 6318

Zaafarany, I. A. & Ghulman, H. A. (2013). Ethoxylated fatty amines as corrosion inhibitors for carbon steel in hydrochloric acid solutions. Int. J. Corros. Scale Inhib., 2,2, pp. 82–91.

Zarrouk, A., Hammouti, B., Lakhlifi, T., Traisnel, M., Vezin, H. & Bentiss, F. (2015). New 1H-pyrrole-2,5-dione derivatives as efficient organic inhibitors of carbon steel corrosion in hydrochloric acid medium: Electrochemical, XPS and DFT studies. Corrosion Science, 90, pp. 572–584.